{"id":1610,"date":"2004-02-02T12:11:58","date_gmt":"2004-02-02T11:11:58","guid":{"rendered":"http:\/\/www.fluoritech.it\/?p=1610"},"modified":"2025-03-27T17:24:50","modified_gmt":"2025-03-27T16:24:50","slug":"new-perfluorovinylethers-through-the-bisfluoroxydifluoromethane-bdm-chemistry","status":"publish","type":"post","link":"https:\/\/www.fluoritech.com\/?p=1610","title":{"rendered":"New perfluorovinylethers through the bis(fluoroxy)difluoromethane (BDM) chemistry"},"content":{"rendered":"

 <\/p>\n

<\/p>\n

\"\"<\/a><\/p>\n

Author(s):<\/span><\/span> Navarrini, W<\/span>; Corti, S.<\/span><\/p>\n

Source: <\/span><\/span>JOURNAL OF FLUORINE CHEMISTRY <\/span><\/p>\n

Volume:<\/span> 125 Issue:<\/span> 2 Pages:<\/span> 189-197 <\/span><\/p>\n

DOI:<\/span><\/span> 10.1016\/j.jfluchem.2003.07.011 Published:<\/span> FEB 2 2004<\/span><\/p>\n

ABSTRACT:<\/p>\n

In the present work we give an overview of the CF2(OF)(2) radical reactivity and report the synthesis of new perfluorovinylethers. CF2=CF-OCF2OCF2CF3 and CF2=CF-OCF2OCF2CF2OCF3 are prepared in a semi-continuous methodology starting from CF2(OF)(2). These highly reactive vinylethers are characterized by the OCF2O group directly bonded to the insaturation. For this reason they are excellent candidates for the preparation of very low T-g perfluororubbers.<\/p>\n

http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113903002732<\/p>\n

\"\"<\/a><\/p>\n

Author(s): Navarrini, W; Corti, S.<\/p>\n

Source: JOURNAL OF FLUORINE CHEMISTRY<\/p>\n

Volume: 125 Issue: 2 Pages: 189-197<\/p>\n

DOI: 10.1016\/j.jfluchem.2003.07.011 Published: FEB 2 2004<\/p>\n

ABSTRACT:<\/p>\n

In the present work we give an overview of the CF2(OF)(2) radical reactivity and report the synthesis of new perfluorovinylethers. CF2=CF-OCF2OCF2CF3 and CF2=CF-OCF2OCF2CF2OCF3 are prepared in a semi-continuous methodology starting from CF2(OF)(2). These highly reactive vinylethers are characterized by the OCF2O group directly bonded to the insaturation. For this reason they are excellent candidates for the preparation of very low T-g perfluororubbers.<\/p>\n

http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113903002732<\/p>\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

  Author(s): Navarrini, W; Corti, S. Source: JOURNAL OF FLUORINE CHEMISTRY Volume: 125 Issue: 2 Pages: 189-197 DOI: 10.1016\/j.jfluchem.2003.07.011 Published: FEB 2 2004 ABSTRACT: In the present work we give an overview of the CF2(OF)(2) radical reactivity and report the synthesis of new perfluorovinylethers. CF2=CF-OCF2OCF2CF3 and CF2=CF-OCF2OCF2CF2OCF3 are prepared in a semi-continuous methodology starting from […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"saved_in_kubio":false,"footnotes":""},"categories":[18],"tags":[],"class_list":["post-1610","post","type-post","status-publish","format-standard","hentry","category-papers-2004"],"_links":{"self":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1610","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1610"}],"version-history":[{"count":11,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1610\/revisions"}],"predecessor-version":[{"id":3843,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1610\/revisions\/3843"}],"wp:attachment":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1610"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1610"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1610"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}