{"id":1623,"date":"2005-12-01T13:17:59","date_gmt":"2005-12-01T12:17:59","guid":{"rendered":"http:\/\/www.fluoritech.it\/?p=1623"},"modified":"2025-03-27T17:23:34","modified_gmt":"2025-03-27T16:23:34","slug":"new-catalytic-alkylation-of-in-situ-generated-perfluoro-alkyloxy-anions-and-perfluoro-carbanions","status":"publish","type":"post","link":"https:\/\/www.fluoritech.com\/?p=1623","title":{"rendered":"New catalytic alkylation of in situ generated perfluoro-alkyloxy-anions and perfluoro-carbanions"},"content":{"rendered":"<p><!--:en--><\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113905002551\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-1624\" title=\"Nuova immagine (1)\" src=\"http:\/\/www.fluoritech.it\/wp-content\/uploads\/2013\/11\/Nuova-immagine-1.png\" alt=\"\" width=\"185\" height=\"245\" \/><\/a><\/p>\n<p>Author(s): Galimberti, M; Fontana, G; Resnati, G; Navarrini, W.<\/p>\n<p>Source: JOURNAL OF FLUORINE CHEMISTRY<\/p>\n<p>Volume: 126 Issue: 11-12 Pages: 1578-1586<\/p>\n<p>DOI: 10.1016\/j.jfluchem.2005.09.005 Published: DEC 2005<\/p>\n<p>ABSTRACT:<\/p>\n<p style=\"text-align: justify;\">Alkyl fluoroformates RHOC(O)F are a new family of excellent alkylating agents. Perfluoroacyl fluorides, selected perfluoroketones and fluoroolefins can be alkylated to hydrofluoroethers R-F-O-R-H and hydrofluoroalkanes R-F-R-H, respectively. Potassium fluoride and cesium fluorides catalysts in glymes at 50-100 degrees C are the preferred experimental conditions.<\/p>\n<p>http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113905002551<\/p>\n<p><!--:--><!--:it--><a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113905002551\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter\" title=\"Nuova immagine (1)\" src=\"http:\/\/www.fluoritech.it\/wp-content\/uploads\/2013\/11\/Nuova-immagine-1.png\" alt=\"\" width=\"185\" height=\"245\" \/><\/a> Author(s): Galimberti, M; Fontana, G; Resnati, G; Navarrini, W.<\/p>\n<p>Source: JOURNAL OF FLUORINE CHEMISTRY<\/p>\n<p>Volume: 126 Issue: 11-12 Pages: 1578-1586<\/p>\n<p>DOI: 10.1016\/j.jfluchem.2005.09.005 Published: DEC 2005<\/p>\n<p>ABSTRACT:<\/p>\n<p style=\"text-align: justify;\">Alkyl fluoroformates RHOC(O)F are a new family of excellent alkylating agents. Perfluoroacyl fluorides, selected perfluoroketones and fluoroolefins can be alkylated to hydrofluoroethers R-F-O-R-H and hydrofluoroalkanes R-F-R-H, respectively. Potassium fluoride and cesium fluorides catalysts in glymes at 50-100 degrees C are the preferred experimental conditions.<\/p>\n<p>http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0022113905002551<\/p>\n<p><!--:--><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Author(s): Galimberti, M; Fontana, G; Resnati, G; Navarrini, W. Source: JOURNAL OF FLUORINE CHEMISTRY Volume: 126 Issue: 11-12 Pages: 1578-1586 DOI: 10.1016\/j.jfluchem.2005.09.005 Published: DEC 2005 ABSTRACT: Alkyl fluoroformates RHOC(O)F are a new family of excellent alkylating agents. Perfluoroacyl fluorides, selected perfluoroketones and fluoroolefins can be alkylated to hydrofluoroethers R-F-O-R-H and hydrofluoroalkanes R-F-R-H, respectively. Potassium fluoride [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"saved_in_kubio":false,"footnotes":""},"categories":[19],"tags":[],"class_list":["post-1623","post","type-post","status-publish","format-standard","hentry","category-papers-2005"],"_links":{"self":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1623","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1623"}],"version-history":[{"count":5,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1623\/revisions"}],"predecessor-version":[{"id":3833,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=\/wp\/v2\/posts\/1623\/revisions\/3833"}],"wp:attachment":[{"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1623"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1623"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.fluoritech.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1623"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}